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Zhang et al. 1991

Zhang, Z., Liu, R., Huie, R.E. and Kurylo, M.J. (1991). Rate constants for the gas phase reactions of the OH radical with CF₃CF₂CHCl₂ (HCFC-225ca) and CF₂ClCF₂CHClF (HCFC-225cb). Geophysical Research Letters 18: doi: 10.1029/90GL02647. issn: 0094-8276.

Rate constants have been measured for the gas phase reactions of the hydroxyl radical (OH) with the hydrochlorofluorocarbons CF3CF2CHCl2 (HCFC-225ca) over the temperature range 270 to 400 K and CF2CLCF2CHClF (HCFC-225cb) over the temperature range 298 to 400 K. The Arrhenius expressions k(225ca)=(1.92¿0.52)¿10-12 exp(-1290¿90/T) cm3 molecule-1 s-1 and k(225cb)=(6.75¿3.70) ¿10-13 exp (-1300¿180/T) cm3 molecule-1 s-1 were derived from the kinetic data.

BACKGROUND DATA FILES

	Abstract

Keywords
Atmospheric Composition and Structure, Troposphere—composition and chemistry

Journal
Geophysical Research Letters
http://www.agu.org/journals/gl/

Publisher
American Geophysical Union
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