In this letter, data from the Halogen Occultation Experiment (HALOE) and the Particle Environment Monitor on the Upper Atmospheric Research Satellite are presented. Five years of data from each instrument have been used to create high-latitude maps of Nitric Oxide (NO) mass mixing ratio and electron impact and bremsstrahlung ionization rates as a function of altitude and Kp. We show that enhancements in NO at 100 km are coupled to the auroral oval and to increases in the local ionization rate, with both the peak in the ionization rate and NO mass mixing ratio occuring in the dawn magnetic local time sector between 60¿ and 70¿ magnetic latitude. Below this altitude, the NO is shown to be enhanced at lower latitudes and sunward of the dawn-dusk meridian, most likely due to solar illumination. Above 100 km, the NO density enhancement stays in approximately the same MLT sector, while the peak ionization rate expands in MLT towards the night side. This is attributed to a build up of NO created by particle precipitation during the night, which is corotated towards the dawn region. ¿ 1999 American Geophysical Union