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Lindner & Jakosky 1985
Lindner, B.L. and Jakosky, B.M. (1985). Martian atmospheric photochemistry and composition during periods of low obliquity. Journal of Geophysical Research 90: doi: 10.1029/JA090iA04p03435. issn: 0148-0227.

During periods of low obliquity, previous work has shown that martian CO2 partial pressures decreased to 0.1 mbar; CO2 partial pressures decreased to 0.02 mbar prior to the formation of the Tharsis bulge. The permanent polar caps act as a cold trap and projected global average water vapor abundances drop to possibly as low as 10-5 precipitable &mgr;m. As a result, the odd hydrogen catalytic cycle would not be effective at recombining CO and O back into CO2, and as much as 0.12 mbar of CO and 0.06 mbar of O2 could exist. These increased abundances would radically affect surface oxidation, change the lower atmospheric thermal structure, and completely alter the upper atmosphere.

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Journal of Geophysical Research
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