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Dickinson et al. 1990
Dickinson, J.E., Scarfe, C.M. and McMillian, P. (1990). Physical properties and structure of K2Si4O9 melt quenched from pressures up to 2.4 GPa. Journal of Geophysical Research 95: doi: 10.1029/90JB00307. issn: 0148-0227.

Melt vicosities and densities of isobarically quenched melts (glasses) have been determined for K2Si2O9 up to pressures of 2.4 GPa. At 1200¿C, melt viscosity decreases linearly from 1700 P at 1 atm to 310 P at 2.4 GPa. The increase in glass density with increasing pressure is described by a Birch-Murnaghan equation of state with values of the 1-atm bulk modulus and its pressure derivative equal to 32.5 GPa and 7.6, respectively. The structure of the quenched melts was investigated using Raman spectroscopy. Scattering in the 900--1000-cm-1 region increases in intensity with increasing pressure, and a new band develops at 940 cm-1, suggesting an increase in Q2 species, perhaps accompanied by the presence of Si in high coordination. In the low-frequency region the 520-cm-1 band of the 1-atm glass increases slightly in frequency with pressure, and a distinct shoulder at 470 cm-1 develops on this band. These observations suggest an increase in the number of Q4 species and a narrowing of the SiOSi bond angle within Q3 groups in the glass. The structural changes are consitent with a shift in the silicate species disproportionation equilibrium, 2Q3=Q4+Q2, to the right with increasing pressure, and the changes provide a mechanism for explaining the observed variations in viscosity and glass density. ¿American Geophysical Union 1990

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Keywords
Mineralogy and Petrology, Crystal chemistry
Journal
Journal of Geophysical Research
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American Geophysical Union
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