With the aim to enhance interpretation of fragmentation mechanisms during explosive volcanism from size and shape characteristics of pyroclasts experimental studies have been conducted using remelted volcanic rock (olivine-melilitite). The melt was fragmented and ejected from a crucible by the controlled release of pressurized air volumes (method 1) or by controlled generation of phreatomagmatic explosions (Molten Fuel Coolant Interaction (MFCI); method 2). Both methods were adjusted so that the ejection history of the melt was identical in both cases. The experiments demonstrate that exclusively during MFCI, angular particles in the grain size interval 32 to 130 μm are generated that show surface textures dominated by cracks and pitting. The physical process of their generation is described as a brittle process acting at cooling rates of >106 K/s, at stress rates well above 3 GPa/m2, and during ~700 μs. In this time period the emission of intense shock waves in the megahertz range was detected, releasing kinetic energy of >1000 J. By both experimental methods, three more types of particles were produced in addition, which could be identified and related to the acceleration and ejection history of the melt: spherical particles, elongated particles, and Pele's hair. Abundance and grain size distribution of these particles were found to be proportional to the rate of acceleration and the speed of ejection but were not influenced by the experimental method used. Pele's hair occurred at ejection speeds of >75 m/s.¿ 1997 American Geophysical Union