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Frost et al. 1998
Frost, D.J., Fei, Y., Frost, D.J. and Fei, Y. (1998). Stability of phase D at high pressure and high temperature. Journal of Geophysical Research 103: doi: 10.1029/98JB00077. issn: 0148-0227.

We have determined the stability of the dense hydrous magnesium silicate phase D in a Mg2SiO4+20.5 wt% H2O composition between 16 and 25 GPa at 900¿--1400 ¿C. Phase D coexists with superhydrous phase B and a Mg-rich liquid to temperatures of 1000 ¿C at 17 GPa and 1400 ¿C at 26 GPa. Experiments in an externally heated diamond-anvil cell confirm that phase D is stable to pressures of at least 50 GPa at 930 ¿C. From static compression measurements, the zero-pressure bulk modulus of phase D was determined as 200¿7 GPa. We also present evidence that phase D is identical to phase F <Kanzaki, 1991> and phase G <Kudoh et al., 1997a; Ohtani et al., 1997>. The high-pressure and high-temperature stability of phase D makes it eminently suitable as a hydrous phase which is stable within subducting lithosphere, in the transition zone, and in the lower mantle. The positive pressure-temperature stability slope of phase D, determined in this study, indicates that it is potentially stable at temperatures much greater than 1400 ¿C in the lower mantle. ¿ 1998 American Geophysical Union

BACKGROUND DATA FILES

Abstract

Keywords
Mineralogy and Petrology, Crystal chemistry, Mineral Physics, High-pressure behavior, Mineral Physics, Optical, infrared, and Raman spectroscopy, Mineralogy and Petrology, Experimental mineralogy and petrology
Journal
Journal of Geophysical Research
http://www.agu.org/journals/jb/
Publisher
American Geophysical Union
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