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Munger et al. 1996
Munger, J.W., Wofsy, S.C., Bakwin, P.S., Fan, S., Goulden, M.L., Daube, B.C., Goldstein, A.H., Moore, K.E. and Fitzjarrald, D.R. (1996). Atmospheric deposition of reactive nitrogen oxides and ozone in a temperate deciduous forest and a subarctic woodland: 1. Measurements and mechanisms. Journal of Geophysical Research 101: doi: 10.1029/96JD00230. issn: 0148-0227.

We present 5 years of NOy and O3 eddy flux and concentration measurements and NOx concentration measurements at Harvard Forest (1990--1994), a mixed deciduous forest in central Massachusetts, and 2 months of data for a spruce woodland near Schefferville, Quebec, during the NASA ABLE3B/Northern Wetlands Study (1990). Mean midday values of net dry NOy flux from atmosphere to canopy were 3.4 and 3.2 μmole m-2 hr-1 at Harvard Forest in summer and winter, respectively, and 0.5 μmole m-2 hr-1 at Schefferville during summer. Nighttime values were 1.3, 2.0, and 0.15 μmole m-2 hr-1, respectively. For 1990--1994, the net annual dry deposition of nitrogen oxides was 17.9 mmole m-2 yr-1 (2.49 kgN ha-1 y-1). Oxidized species such as HNO3 dominated N deposition, with minor contributions from direct deposition of NO2. Emissions of NO from the forest soil were negligible compared to deposition. Comparison of NOy deposition at Harvard Forest and Schefferville and analysis of the dependence on meteorological parameters show that anthropogenic sources dominate the nitrogen oxide inputs over much of North America. Heterogeneous reactions account for >90% of the conversion of NO2 to HNO3 in winter, leading to rates for dry deposition of NOy similar to fluxes in summer despite 10-fold decrease in OH concentrations. In summer, formation of HNO3 by heterogeneous reactions (mainly at night) could provide 25--45% of the NO2 oxidation. ¿ American Geophysical Union 1996

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Keywords
Atmospheric Composition and Structure, Biosphere/atmosphere interactions, Atmospheric Composition and Structure, Pollution—urban and regional, Atmospheric Composition and Structure, Troposphere—composition and chemistry, Atmospheric Composition and Structure, Instruments and techniques
Journal
Journal of Geophysical Research
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American Geophysical Union
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