Further laboratory measurements of charge transfer between ice crystals and riming graupel pellets, which are thought to be associated with the electrification processes within thunderstorms, have been carried out in the University of Manchester Institute of Science and Technology cloud chamber. In experiments with clouds in the temperature range -6 ¿C to -26 ¿C, the supercooled droplet spectrum has been extended to larger droplet sizes, above 60 μm maximum diameter, representative of the broadest spectrum observed in some thunderstorm cloud charging regions. The results indicate that at temperatures from -6 ¿C to -18 ¿C, broadening the droplet spectrum leads to negative graupel charging at higher values of cloud effective liquid water content than has been reported in previous laboratory studies. The significance of the result is that in order to ensure that laboratory experiments simulate as closely as possible the thunderstorm cloud microphysical environment, attention must be paid to the spectrum of droplets used. Two mechanisms of charge transfer that may account for this behavior are discussed, the relative growth rate theory and the surface splinter theory, and both are found to be compatible with the results on the assumption that the larger droplets lead to a reduction in the rate of vapor deposition to the riming surface. Analysis of the implications of these results to thunderstorm electrification requires more details of the evolution of droplet spectra in thunderclouds, their spatial and temporal development and location relative to observed regions of electrification. ¿ 1998 American Geophysical Union