The actinic flux must be distinguished from other radiometric quantities such as the irradiance. This distinction shows that (1) a fraction of the recent atmospheric chemistry literature contains improperly calculated rates of photodissociation, and (2) photodissociation rate coefficients inside clouds, and particularly inside cloud droplets, can frequently exceed the clear-sky values, in contrast to current usage in cloud chemistry models. Both of these findings are traceable to the ~2 cos &thgr; factor incurred in the actinic flux (but not in the irradiance) when the solar beam is scattered and diffused into nearly isotropic light. ¿American Geophysical Union 1987 |