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Kentarchos & Roelofs 2002
Kentarchos, A.S. and Roelofs, G.J. (2002). Impact of aircraft NOx emissions on tropospheric ozone calculated with a chemistry-general circulation model: Sensitivity to higher hydrocarbon chemistry. Journal of Geophysical Research 107: doi: 10.1029/2001JD000828. issn: 0148-0227.

A three-dimensional chemistry-general circulation model has been employed to estimate the impact of current aircraft NOx emissions on tropospheric ozone. The model contains a representation of higher hydrocarbon chemistry, implemented by means of the Carbon Bond Mechanism 4 (CBM4), in order to investigate the potential effect of higher hydrocarbons on aircraft-induced ozone changes. Aircraft NOx emissions increase background NOX (= NO + NO2 + NO3 + 2N2O5 + HNO4) concentrations by 50--70 pptv in the upper troposphere over the Northern Hemisphere, and contribute up to 3 ppbv to upper tropospheric background ozone levels. When higher hydrocarbon chemistry is considered in the simulation, the aircraft-induced ozone perturbations are higher by ~12% during summer and the aircraft-induced ozone production efficiency per NOx molecule increases by ~20%, when compared to a simulation without higher hydrocarbon chemistry.

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Abstract

Keywords
Atmospheric Composition and Structure, Troposphere--composition and chemistry, Atmospheric Composition and Structure, Constituent sources and sinks, Meteorology and Atmospheric Dynamics, Numerical modeling and data assimilation
Journal
Journal of Geophysical Research
http://www.agu.org/journals/jb/
Publisher
American Geophysical Union
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