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Detailed Reference Information |
Lämmerzahl, P., Röckmann, T., Brenninkmeijer, C.A.M., Krankowsky, D. and Mauersberger, K. (2002). Oxygen isotope composition of stratospheric carbon dioxide. Geophysical Research Letters 29: doi: 10.1029/2001GL014343. issn: 0094-8276. |
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Heavy oxygen isotope enrichment in stratospheric CO2 has been identified in the past as a direct result of the large O3 isotope anomaly though no simultaneous measurements are known. Results from 8 stratospheric balloon flights at two latitudes are reported that provide now a complete oxygen isotope analysis of both gases. An unambiguous, very tight correlation between enrichments of 17O and 18O in CO2 has been found. The large ratio δ17O/δ18O of 1.71 ¿ 0.03 shows a faster transfer of 17O than of 18O into CO2 and establishes a standard throughout the lower and middle stratosphere between midlatitudes and high northern latitudes. Ozone isotope transfer can now be treated in models with reliable atmospheric data. |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Biosphere/atmosphere interactions, Atmospheric Composition and Structure, Chemical kinetic and photochemical properties, Atmospheric Composition and Structure, Middle atmosphere--composition and chemistry |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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