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Detailed Reference Information |
Russell, K.M., Keene, W.C., Maben, J.R., Galloway, J.N. and Moody, J.L. (2003). Phase partitioning and dry deposition of atmospheric nitrogen at the mid-Atlantic U.S. coast. Journal of Geophysical Research 108: doi: 10.1029/2003JD003736. issn: 0148-0227. |
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The deposition of atmospheric nitrogen contributes significantly to total nitrogen (TN) entering U.S. coastal water bodies. Nitrogen inputs via wet deposition are well quantified but dry-deposition fluxes are uncertain. In this study, dry fluxes of major atmospheric nitrogen species (including gaseous NH3 and HNO3 and particulate NH4+, NO3-, NO2-, and organic nitrogen (ON)) were quantified during a 2-week summer sampling period at Lewes, Delaware, on the mid-Atlantic U.S. coast. Results indicate that dry deposition contributed approximately 43% to total atmospheric nitrogen deposition. Under all flow conditions, NH3(g) accounted for the largest fraction of TN dry deposition (averaging 60%); HNO3(g) and NO3- also contributed considerably (averaging 25 and 8%, respectively). During onshore flow, scavenging of HNO3(g) by sea-salt aerosols shifted the phase partitioning and relative dry fluxes of total NO3 (HNO3(g) + NO3-) toward particulate NO3-. The mass-weighted deposition velocities for particulate NO3- (associated primarily with sea-salt size fractions) were similar to those of HNO3(g). Consequently, phase changes did not substantially alter the dry-deposition fluxes of total NO3. In light of these results, dry-deposition monitoring programs at coastal locations should (1) quantify NH3(g) deposition; (2) reliably sample supermicron particles (with which most particulate NO3- is associated); and (3) apply deposition models for particulate nitrogen that are consistent with corresponding size distributions. |
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BACKGROUND DATA FILES |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Aerosols and particles (0345, 4801), Atmospheric Composition and Structure, Air/sea constituent fluxes (3339, 4504), Oceanography, Biological and Chemical, Nutrients and nutrient cycling |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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