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Detailed Reference Information |
Dassau, T.M., Sumner, A.L., Koeniger, S.L., Shepson, P.B., Yang, J., Honrath, R.E., Cullen, N.J., Steffen, K., Jacobi, H., Frey, M. and Bales, R.C. (2002). Investigation of the role of the snowpack on atmospheric formaldehyde chemistry at Summit, Greenland. Journal of Geophysical Research 107: doi: 10.1029/2002JD002182. issn: 0148-0227. |
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Ambient gas-phase and snow-phase measurements of formaldehyde (HCHO) were conducted at Summit, Greenland, during several summers, in order to understand the role of air-snow exchange on remote tropospheric HCHO and factors that determine snowpack HCHO. To investigate the impact of the known snowpack emission of HCHO, a gas-phase model was developed that includes known chemistry relevant to Summit and that is constrained by data from the 1999 and 2000 field campaigns. This gas-phase-only model does not account for the high ambient levels of HCHO observed at Summit for several previous measurement campaigns, predicting approximately 150 ppt from predominantly CH4 chemistry, which is ~25--50% of the observed concentrations for several years. Simulations were conducted that included a snowpack flux of HCHO based on HCHO flux measurements from 2000 and 1996. Using the fluxes obtained for 2000, the snowpack does not appear to be a substantial source of gas-phase HCHO in summer. The 1996 flux estimates predict much higher HCHO concentrations, but with a strong diel cycle that does not match the observations. Thus, we conclude that, although the flux of HCHO from the surface likely has a significant impact on atmospheric HCHO above the snowpack, the time--dependent fluxes need to be better understood and quantified. It is also necessary to identify the HCHO precursors so we can better understand the nature and importance of snowpack photochemistry. |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Constituent sources and sinks, Atmospheric Composition and Structure, Troposphere--composition and chemistry, Hydrology, Snow and ice, Meteorology and Atmospheric Dynamics, Theoretical modeling |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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