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Detailed Reference Information |
Hwang, H. and Ro, C. (2005). Single-particle characterization of four aerosol samples collected in ChunCheon, Korea, during Asian dust storm events in 2002. Journal of Geophysical Research 110: doi: 10.1029/2005JD006050. issn: 0148-0227. |
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A single-particle analytical technique, named low-Z particle electron probe X-ray microanalysis (low-Z particle EPMA), employing an ultrathin window X-ray detector and enabling the quantitative determination of even low-Z elements such as C, N, and O, was applied to characterize "Asian dust" samples, collected in ChunCheon, Korea, during four Asian dust storm events on 21 March, 9 April, 17 April, and 11 November in 2002. In this study, it is demonstrated that single-particle analysis using the low-Z particle EPMA provides detailed information on various types of chemical species in the samples. The most abundantly encountered particles, both in coarse and fine fractions, are soil-derived particles such as aluminosilicates and silicon dioxide, except for the sample collected on 11 November 2002, where reacted CaCO3 particles are the most abundantly encountered. All four samples are found to have experienced chemical modifications during long-range transport because the samples contain a significant number of particles composed of chemical species, such as nitrate and sulfate, which resulted from atmospheric reactions of CaCO3 and sea-salt particles. This finding implies that CaCO3 and sea-salt particles reacted with sulfur and nitrogen oxide species during long-range transport. The sample collected on 11 November 2002 experienced the most extensive chemical modification during its transport. For this sample, the overall relative abundances of reacted CaCO3 and reacted sea-salt particles are 29.9% and 23.2%, respectively. In addition to the observation of the reacted CaCO3 and sea-salt particles, reacted K-containing particles are also encountered in this sample. In this work, it is observed that chemical modification of sea-salt particles was more extensive than that of CaCO3 particles. By considering the relative abundances of nitrate- and sulfate-containing particles, nitrate formation from CaCO3 and sea-salt particles in the air is found to be more favorable than sulfate formation. |
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Abstract |
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Keywords
Atmospheric Composition and Structure, Aerosols and particles (0345, 4801, 4906), Atmospheric Composition and Structure, Instruments and techniques, Geochemistry, Composition of aerosols and dust particles, Asian dust, aerosols, single-particle analysis, electron probe X-ray microanalysis, low-Z particle EPMA |
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Publisher
American Geophysical Union 2000 Florida Avenue N.W. Washington, D.C. 20009-1277 USA 1-202-462-6900 1-202-328-0566 service@agu.org |
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