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Zolensky et al. 1993
Zolensky, M., Barrett, R. and Browning, L. (1993). Mineralogy and Composition of Matrix and Chondrule Rims in Carbonaceous Chondrites. Geochimica et Cosmochimica Acta 57(13): 3,123-3,148.
The degree of compositional variation of fine-grained minerals displayed by the members within any carbonaceous chondrite group (i.e., CI, CM, CV, CR) is a direct reflection of the range of aqueous alteration assemblages present. Matrix and fine-grained chondrule rims within any particular carbonaceous chondrite are mineralogically nearly identical to one another, but not necessarily similar in bulk elemental composition, even though they have subsequently experienced post-accretional secondary processing (aqueous alteration) under identical conditions. This may indicate preferential alteration of one component, brecciation, exchange of components between rims and matrix, and/or accretion of matrix and rims from mineralogically or compositionally distinct materials. We propose that CO chondrites experienced parent body conditions of low f(O2), low water/rock ratios, and temperatures below 50-degrees-C. CR chondrites experienced higher water/rock ratios, potentially higher temperatures (less-than-or-equal-to 150-degrees-C), and a wide range of f(O2). The alteration mineralogy of CV chondrites indicates water/rock ratios at the high end (at least) of the range for CR chondrites, Essebi, and MAC 87300. CM chondrites experienced temperatures below 50-degrees-C, low f(O2) and low water/rock ratios, except EET 83334, which probably experienced relatively higher f(O2), and B-7904 and Y-86720, which experienced postalteration temperatures in the range 500-700-degrees-C. Most CI chondrites experienced temperatures between 50 and 150-degrees-C, relatively high water/rock ratios, and variable f(O2) with a late-stage increase in the latter, due possibly to brecciation and consequent release of methane. Y-82162 witnessed post-alteration heating, possibly as high as 400-degrees-C.
BACKGROUND DATA FILES

Abstract

Table 1A
Table 1B
Table 2
Table 3
Table 4
Table 5
Table 6
Table 7

Experimental Procedure
Constraining Geochemical Modeling

Keywords
accretionary dust mantles, aqueous alteration, cm chondrites, chemical variations, surface conditions, allende meteorite, type-3 chondrites, ci chondrites, parent bodies, solar nebula
Journal
Geochimica et Cosmochimica Acta
http://www.elsevier.com/wps/product/cws_home/212
Publisher
Elsevier Science
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The Netherlands
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