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Shonija et al. 2007
Shonija, N.K., Popovicheva, O.B., Persiantseva, N.M., Savel'ev, A.M. and Starik, A.M. (2007). Hydration of aircraft engine soot particles under plume conditions: Effect of sulfuric and nitric acid processing. Journal of Geophysical Research 112. doi: 10.1029/2006JD007217. issn: 0148-0227.

Hydration properties of original engine soot produced by burning TC1 aviation kerosene in aircraft engine combustor are studied under simulated plume conditions. Engine-generated soot demonstrates a high level of water uptake due to the existence of fraction of impurities originating within an engine. It contains 13.5 wt% water soluble compounds including 3.5 wt% organic and inorganic sulfates. Total amount of water vapor absorbed by engine soot particles increases with the temperature decrease in the exhaust plume and reaches 18 wt% at threshold contrail formation conditions. Chemical processing of soot particles in the young plume through the coagulation with sulfate aerosols and H2SO4/H2O heterogeneous nucleation leads to 0.2 wt% of H2SO4 accumulating at high fuel sulfur content. Such a small amount of additional H2SO4 cannot result in the increase of water uptake by the fraction of impurities of engine-generated soot particles but may activate the hydrophobic fraction that originally contains a negligible amount of water soluble compounds. HNO3 processing may compete with H2SO4 in respect to increase of water uptake. It is inferred that the fraction of impurities of engine-generated soot plays a key role in the CCN formation in the aircraft plume.

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Abstract

Keywords
Atmospheric Composition and Structure, Aerosols and particles (0345, 4801, 4906), Atmospheric Processes, Climate change and variability (1616, 1635, 3309, 4215, 4513), Atmospheric Processes, Clouds and aerosols, Mineral Physics, Surfaces and interfaces
Journal
Journal of Geophysical Research
http://www.agu.org/journals/jb/
Publisher
American Geophysical Union
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